High temperature spectroscopy of ensembles of nitrogen-vacancy centers in diamond

نویسندگان

چکیده

We study the spectroscopy of an ensemble negatively charged nitrogen-vacancy centers in diamond at high temperatures between room temperature and [Formula: see text] under vacuum conditions. Spin resonances are studied using optical detection magnetic resonance (ODMR), is employed to radiative transitions. Upon increasing temperature, intensity decay visible infrared decreased. In addition, ODMR frequencies were decreased, phonon line emission shifted higher wavelengths. Density functional theory calculation zero-field splitting parameter ([Formula: text]) revealed that thermal expansion not enough explain shift frequencies. Fitting measured photo-luminescence with theoretical predictions Mott–Seitz model yields value for energy barrier associated nonradiative decay.

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ژورنال

عنوان ژورنال: Journal of Applied Physics

سال: 2023

ISSN: ['1089-7550', '0021-8979', '1520-8850']

DOI: https://doi.org/10.1063/5.0128069